GoldenEye 007 and Perfect Dark are the reason this emulator is famous. They require specific settings:
Place the folders onto the root of your SD card in the following structure: SD:/apps/not64/ : Contains boot.dol , icon.png , and meta.xml . not64 channel installer hot
Now that you have the channel permanently installed, you need to configure Not64 for peak performance. The "Hot" installer usually comes with a default configuration, but you should tweak these settings: GoldenEye 007 and Perfect Dark are the reason
If you want, I can: